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名称:S-(-)-α-苯乙胺
 

纯度:99% 包装:180kg/桶

结构式
             

CAS:   2627-86-3
分子式: C8H11N
分子量:  121.18

中文名称:  S-1-苯乙胺
       S-(-)-α-苯乙胺
                   S(-)-alpha-甲基苄胺


英文名称:  (s)-benzenemethanamin
                    l(-)-alpha-methylbenzylamine 
 
性质描述:  无色透明液体,微溶于水。密度 0.94,熔点-10℃,沸点187-189,折射率1.525-1.527,闪点79,比旋光度-40° (neat)。

质量标准
外观  无色透明液体
含量  ≥99%
[α]D25   -37~-40

用途:手性化合物,医药中间体。

其它信息:
Product Identification
【Product Name】L(-)-alpha-Methylbenzylamine S-1-苯乙胺
【Synonyms】(1S)-1-Phenylethanamine
【CAS】2627-86-3
【Formula】C8H11N
【Molecular Weight】121.18
【EINECS】220-098-0
【Merck】12,6106
【Beilstein/Gmelin】2204907
【Beilstein Reference】4-12-00-02424
【EC Class】harmful, corrosive

Physical and Chemical Properties
【Appearance】Liquid. Mild ammoniacal odor.
【Solubility in water】Very soluble
【Melting Point】-10 ℃
【Boiling Point】187 ℃
【Vapor Pressure】3.0 (20℃)
【Density】0.9762 g/cm3 (17.5℃)
【pKa/pKb】4.25 (pKb)
【Partition Coefficient】1.44
【Heat Of Vaporization】41.9 kJ/mol
【Vapor Density】4.18
【Refractive Index】1.53 (20 ℃)

First Aid Measures
【Ingestion】Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Handling and Storage
【Storage】Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
【Handling】Wash thoroughly after handling. Use only in a well ventilated area. Avoid breathing dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification
【Ingestion】May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
【Inhalation】Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
【Skin】Causes skin burns.
【Eyes】Causes eye burns.
【Hazards】When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】R 21/22 34
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】2735

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Poison Class】4 (Substances and products that must be considered harmful)

Fire Fighting Measures
【Flash Point】71
【Autoignition】355
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
【Fire Potential】Combustible material: may burn but does not ignite readily.

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity
【Disposal Code】5
【Stability】Stable under normal temperatures and pressures. Absorbs carbon dioxide from the air.
【Incompatibilities】Strong oxidizing agents, acids, methanoic acid, oxalic acid), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), halogenated organics (e.g. dibromoethane, hexachlorobenzene, methyl chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), metals (alkali and alkaline, e.g. cesium, potassium, sodium), metals and metal compounds (toxic, e.g. beryllium, lead acetate, nickel carbonyl, tetraethyl lead), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), epoxides (e.g. butyl glycidyl ether), oxidizing agents (strong, e.g. bromine, hydrogen per
【Decomposition】Nitrogen oxides, carbon monoxide, carbon dioxide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】2735
【Hazard Class】8
【Packing Group】I; II; III
【HS Code】2921 49 80



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