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名称:4,6-二氯嘧啶
 

纯度:99% 包装:25kg/桶

结构式
                             

CAS:   1193-21-1
分子式: C4H2Cl2N2
分子量:  148.98

中文名称:  4,6-二氯嘧啶

英文名称:  4,6-dichloropyrimidine

性质描述:  淡黄色至白色结晶体,贮存时会转为黄棕色,熔点64-66℃,沸点75-80℃(72kPa)。不溶于水,溶于甲苯、二甲基甲酰胺和二氯乙烯等溶剂。 

质量标准:
外观   淡黄色至白色结晶
含量   ≥99.0%
熔点           64 - 66℃
炽灼残渣 ≤0.5%
水分    ≤0.5%


用途:      通过串联胺化以及Suzuki-Miyaura交叉偶联反应合成二取代嘧啶的起始原料;也用于涉及二芳基交叉偶联反应的二芳基嘧啶合成。

  用作医药或杀菌剂中间体,用于生产磺胺-6-甲氧嘧啶、杀菌剂嘧菌酯

其它信息:

Product Identification
【Product Name】4,6-Dichloropyrimidine
【Synonyms】4,6-二氯嘧啶
【CAS】1193-21-1
【Formula】C4H2Cl2N2
【Molecular Weight】148.97
【EINECS】214-770-2
【Beilstein/Gmelin】111195
【Beilstein Reference】5-23-05-00346

Physical and Chemical Properties
【Appearance】Solid.
【Solubility in water】Slightly soluble
【Melting Point】64-66℃
【Boiling Point】176℃
【Vapor Pressure】1.5 (25℃)
【Density】1.734 g/cm3
【Partition Coefficient】1.29
【Heat Of Vaporization】39.5 kJ/mol

First Aid Measures
【Ingestion】Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage
【Storage】Store in a cool, dry place. Store in a tightly closed container. Corrosives area.
【Handling】Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.

Hazards Identification
【Ingestion】Causes gastrointestinal tract burns.
【Inhalation】Causes chemical burns to the respiratory tract.
【Skin】Causes skin burns.
【Eyes】Causes eye burns. Lachrymator.
【EC Risk Phrase】R 34 36/37
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】3261

Exposure Controls/Personal Protection
【Personal Protection】Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures
【Flash Point】105℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Use foam, dry chemical, or carbon dioxide.

Accidental Release Measures
【Small spills/leaks】Vacuum or sweep up material and place into a suitable disposal container.

Stability and Reactivity
【Stability】No data.
【Incompatibilities】Strong oxidizing agents, acids, acetic anhydride, acid chlorides, carbon dioxide.
【Decomposition】Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.

Transport Information
【UN Number】3261



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